- Chemical Name 1,4-Dimethyl-2-iodobenzene
- CAS No. 1122-42-5
- Contact Us Inquiry
Cost-effective and customizable 1,4-Dimethyl-2-iodobenzene 1122-42-5 supplier
- Molecular Formula: C8H9I
- Molecular Weight: 232.064
- Appearance/Colour: clear yellow liquid
- Vapor Pressure: 0.115mmHg at 25°C
- Melting Point: -2.9°C (estimate)
- Refractive Index: 1.5980
- Boiling Point: 227.761 °C at 760 mmHg
- Flash Point: 98.229 °C
- PSA： 0.00000
- Density: 1.611 g/cm3
- LogP: 2.90800
1,4-Dimethyl-2-iodobenzene(Cas 1122-42-5) Usage
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Synthesis Reference(s) |
Organic Syntheses, Coll. Vol. 6, p. 709, 1988Tetrahedron Letters, 30, p. 3769, 1989 DOI: 10.1016/S0040-4039(01)80650-X |
InChI:InChI=1/C8H9I/c1-6-3-4-7(2)8(9)5-6/h3-5H,1-2H3
1122-42-5 Relevant articles
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McKillop et al.
, p. 4841 (1971)
-
Efficient and direct iodination of alkyl benzenes using polymer/HIO4 and I2 under mild condition
Bahrami-Nasab, Sepideh,Nazifi, S. Mohamad Reza,Pourali, Ali Reza
, p. 305 - 308 (2014)
An efficient and rapid method has been f...
-
Mascarelli,Longo
, (1938)
-
Iodination of (E)-2,2,5,5-tetramethyl-3,4-diphenylhex-3-ene: Catalytic effects of silver triflate and water in the I2/Ag2SO4 iodination
Sekher, Padmanabhan,Gano, James E.,Luzik Jr., Eddie D.
, p. 3631 - 3636 (1997)
(E)-2,2,5,5-Tetramethyl-3 4-diphenylhex-...
Mild and regioselective iodination of aromatic compounds with N,N′-diiodo-N,N′-1,2-ethanediylbis(p-toluenesulphonamide)
Ghorbani-Vaghei, Ramin
, p. 7529 - 7532 (2003)
N,N′-Diiodo-N,N′-1,2-ethanediylbis(p-tol...
Desulfonyloxyiodination of arenesulfonic acids with mCPBA and molecular iodine
Suzuki, Yuhsuke,Ishiwata, Yoshihide,Moriyama, Katsuhiko,Togo, Hideo
, p. 5950 - 5953 (2010)
Treatment of p-alkylbenzenesulfonic acid...
A comparison of microwave-accelerated and conventionally heated iodination reactions of some arenes and heteroarenes, using ortho-periodic acid as the oxidant
Sosnowski, Maciej,Skulski, Lech
, p. 401 - 406 (2005)
A fast and simple method for the oxidati...
-
Kohlrausch,Pongratz
, (1935)
-
Aromatic iodination using N-iodosaccharin in room temperature ionic liquids
Bailey, Lindsey,Handy, Scott T.
, p. 2413 - 2414 (2011)
More reactive iodination conditions have...
Photochemically Activated Dimagnesium(I) Compounds: Reagents for the Reduction and Selective C?H Bond Activation of Inert Arenes
Jones, Dafydd D. L.,Douair, Iskander,Maron, Laurent,Jones, Cameron
, p. 7087 - 7092 (2021)
The photochemical activation of dimagnes...
Synthesis of polysubstituted iodobenzene derivatives from alkynylsilanes and 1,3-dienes via diels-alder/oxidation/iodination reaction sequence
Mockel, Robert,Hilt, Gerhard
, p. 1644 - 1647 (2015)
The cobalt-catalyzed Diels-Alder reactio...
Iodination of activated aromatic compounds using sodium peroxodisulfate and iodine: An efficient way to iodinate alkylated calix[4]arenes
Barton, Olaf G.,Mattay, Jochen
, p. 110 - 114 (2008)
A simple method for the iodination of ac...
Effective and regioselective iodination of arenes using iron(III) nitrate in the presence of tungstophosphoric acid
Jafarzadeh, Mohammad,Amani, Kamal,Nikpour, Farzad
, p. 1808 - 1811 (2005)
An easy, cheap, and effective method for...
Lower Nitrogen Oxide Species as Catalysts in a Convenient Procedure for the Iodination of Aromatic Compounds
Radner, Finn
, p. 3548 - 3553 (1988)
A simple method for the iodination of ar...
Iodination of activated arenes using silfen: An improved protocol
Tilve, Rutuja D.,Alexander, Varughese M.,Khadilkar, Bhushan M.
, p. 9457 - 9459 (2002)
A simple and direct method for the iodin...
R4NHal/NOHSO4: A Usable System for Halogenation of Isoxazoles, Pyrazoles, and beyond
Bondarenko, Oksana B.,Karetnikov, Georgy L.,Komarov, Arseniy I.,Pavlov, Aleksandr I.,Nikolaeva, Svetlana N.
supporting information, p. 322 - 332 (2021/01/14)
A new convenient and versatile halogenat...
Metal-Free, Oxidant-Free, and Controllable Graphene Oxide Catalyzed Direct Iodination of Arenes and Ketones
Zhang, Jingyu,Li, Shiguang,Deng, Guo-Jun,Gong, Hang
, p. 376 - 380 (2017/12/07)
A direct, metal-free, and oxidant-free m...
Aliphatic C-H Bond Iodination by a N-Iodoamide and Isolation of an Elusive N-Amidyl Radical
Artaryan, Alexander,Mardyukov, Artur,Kulbitski, Kseniya,Avigdori, Idan,Nisnevich, Gennady A.,Schreiner, Peter R.,Gandelman, Mark
supporting information, p. 7093 - 7100 (2017/07/26)
Contrary to C-H chlorination and bromina...
1122-42-5 Process route
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(2,5-dimethylphenyl)(4'-methoxyphenyl)iodonium hexafluorophosphate
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420-87-1
sodium 2,2,2-trifluoroethanolate
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1122-42-5
2-iodo-p-xylene
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696-62-8
para-iodoanisole
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79644-38-5
(2,5-Dimethylphenyl)-(2,2,2-trifluorethyl)-ether
| Conditions | Yield |
|---|---|
|
In
[D3]acetonitrile;
at 45 ℃;
regioselective reaction;
Inert atmosphere;
Darkness;
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80 %Spectr.
|
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(2,5-dimethylphenyl)(4'-methoxyphenyl)iodonium hexafluorophosphate
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10534-59-5
tetrabutylammonium acetate
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877-48-5
2,5-dimethylphenyl acetate
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-
1122-42-5
2-iodo-p-xylene
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696-62-8
para-iodoanisole
| Conditions | Yield |
|---|---|
|
In
[D3]acetonitrile;
at 80 ℃;
regioselective reaction;
Inert atmosphere;
Darkness;
|
> 99 %Spectr.
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1122-42-5 Upstream products
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106-42-3
para-xylene
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95-78-3
2,5-Dimethylaniline
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75-03-6
ethyl iodide
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2712-78-9
bis-[(trifluoroacetoxy)iodo]benzene
1122-42-5 Downstream products
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127938-44-7
2-dichloroiodanyl-1,4-dimethyl-benzene
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1124-08-9
2,5-diiodo-p-xylene
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699119-05-6
1-bromo-4-iodo-2,5-dimethylbenzene
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6311-51-9
1-iodo-2,5-dimethyl-4-nitro-benzene
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